Synthesis, crystal structure, and nonlinear optical properties of Li6CuB4O10: a congruently melting compound with isolated [CuB4O10]6- units.

نویسندگان

  • Shilie Pan
  • Jared P Smit
  • Byron Watkins
  • Michael R Marvel
  • Charlotte L Stern
  • Kenneth R Poeppelmeier
چکیده

Single crystals of Li(6)CuB(4)O(10) have been synthesized, and its crystal structure has been determined. Li(6)CuB(4)O(10) crystallizes in the non-centrosymmetric triclinic space group P1 (No. 1). The structure consists of isolated [CuB(4)O(10)](6)(-) polyanions that are bridged by six LiO(4) tetrahedra. Li(6)CuB(4)O(10) is a congruently melting compound. It produces SHG intensity similar to that produced by KH(2)PO(4) and is phase-matchable.

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عنوان ژورنال:
  • Journal of the American Chemical Society

دوره 128 35  شماره 

صفحات  -

تاریخ انتشار 2006